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Structure and properties of iron-nickel invar sintered alloys

https://doi.org/10.22349/1994-6716-2019-99-3-07-13

Abstract

The structure and physicomechanical properties of iron-nickel invar alloys obtained by sintering powders are investigated. It is shown that during sintering of iron and nickel powders, an alloy with a facecentered cubic structure is formed, whose lattice parameters correspond to invariant compositions. The resulting invar alloys are characterized by hardness, Young’s modulus, and thermal expansion coefficient comparable with the literature data. The Young’s modulus is in the range from 83 to 126 GPA, depending on the composition and sintering temperature, the coefficient of thermal expansion in the temperature range from 0 to 150°C is 1.1·10–6°C–1, in the temperature range from 300 to 500°С is 15.8·10–6°С–1. It is shown that a phase transition occurs associated with the loss of magnetic properties at a temperature of 225°C.

About the Authors

E. V. Abdulmenova
Institute of Strength Physics and Materials Science of the Siberian Branch of the Russian Academy of Sciences (ISPMS SB RAS), National Research Tomsk Polytechnic University (NR TPU)
Russian Federation
2/4 Akademichesky Ave., 634055 Tomsk, Russian Federation

30 Lenina Ave., 634034 Tomsk, Russian Federation



O. Yu. Vaulina
National Research Tomsk Polytechnic University (NR TPU)
Russian Federation
Cand. Sc. (Eng.)

30 Lenina Ave., 634034 Tomsk, Russian Federation


S. N. Kulkov
Institute of Strength Physics and Materials Science of the Siberian Branch of the Russian Academy of Sciences (ISPMS SB RAS), National Research Tomsk Polytechnic University (NR TPU)
Russian Federation

Dr. Sc. (Phys.-Math.)

2/4 Akademichesky Ave., 634055 Tomsk, Russian Federation 

30 Lenina Ave., 634034 Tomsk, Russian Federation 



References

1. Guillaume C. E. Recherches sur les aciers au nickel. Dilatations aux temperatures elevees: resistance electrique // Comptes rendus de l'Académie des Sciences. – 1897. – N 125. – P. 235–238.

2. Maslyuk V. A., Panasyuk O. A., Vlasova , O. V. Physical, technological and magnetic properties of powder iron–nickel alloys // Powder Metallurgy and Metal Ceramics. – 2003. – N 42. – P. 536–539.

3. German R. M. Powder Metallurgy and Particulate Materials Processing. – Metal Powder Industries Federation. – 2005. – Princeton. – New Jersey. – 528 p.

4. Chang I., Zhao Y. Advances in powder metallurgy: Properties, processing and applications. – Woodhead Publishing Limited. – 2013. – 604 p.

5. Кипарисов С. С. Порошковая металлургия. – М.: Металлургия, 1980. – 496 c.

6. Synthesis of controlled-chemistry ultrafine Fe·Ni1−x ferromagnetic powders / C. Duhamel, Y. Champion et al. // Journal of Alloys and Compounds. – 2005. – N 393. – P. 204–210.

7. Mechanical and functional properties of Invar alloy for μ-MIM / J. Hidalgo, A. Jiménez - Morales, T. Barriere et al. // Powder Metallurgy. – 2014. – N 2. – P. 127–136.

8. Oglezneva S.A., Saenkov K.L., Grevnov L.M., Issledovanie fiziko-mekhanicheskikh svoistv i temperaturnykh fazovykh prevrashchenii poroshkovykh Fe-Ni-splavov [Investigation of the physicomechanical properties and temperature phase transformations of powder Fe-Ni alloys], Vestnik PNIPU (Perm University), 2017, No 3, pp. 34–48.

9. German R. Metal powder injection molding (MIM): key trends and markets: Handbook of metal injection molding. – Woodhead Publishing Limited, 2012. – P. 1–12.

10. Randall M. Markets applications, and financial aspects of global metal powder injection moulding (MIM) technologies. – MPR, 2012. – P. 18–26.

11. Petzoldt F. Current status and future perspectives of the MIM technology // Ceram. Forum Int. – 2012. – N 89. – P. 11–15.

12. Scherrer P. Bestimmung der Größe und der inneren Struktur von Kolloidteilchen mittels Röntgenstrahlen // Göttinger Nachrichten Gesellschaft. – 1918. – N 2. – P. 98–101.

13. Stokes A. R., Wilso n A. J. C. The diffraction of X rays by distorted crystal aggregates // Proceedings of the Physical Society, 1944. – P. 174–181.

14. State Standard GOST 8.748-2011 (ISO 14577-1:2002). Metally i splavy: Izmerenie tverdosti i drugikh kharakteristik materialov pri instrumentalnom indentirovanii [Metals and alloys: Measurement of hardness and other characteristics of materials with instrumental indentation], Moscow, 2013.

15. Koritsky Yu.V., Spravochnik po elektrotekhnicheskim materialam [Reference book on electrical

16. materials], Leningrad: Energoatomizdat, 1988, V. 3.

17. Chamberod A., Laugier J., Penis son J. M. Electron irradiation effects on iron-nickel invar alloys // Journal of Magnetism and Magnetic Materials. – 1979. – N 10. – P. 139–144.

18. Prabhu Y., Rao K. X-Ray analysis by Williamson-Hall and size-Strain plot methods of ZnO nanoparticles with fuel variation // World Journal of Nano Science and Engineering. – 2014. – N 4. – P. 21–28.

19. Davies J. R. Special-purpose nickel alloys // ASM Specialty Handbook: Nickel, Cobalt and their Alloys. – ASM International, 2000. – 421 p.

20. Davies J. R. 36% nickel-iron allow for low temperature service // ASM Specialty Handbook: Nickel, Cobalt and their Alloys. – ASM International, 2000. – 421 p.

21. Hidalgo J., Jimenez-Morales A. Water soluble Invar 36 feedstock development for µ-PIM // Journal of Materials Processing Technology. – 2014. – N 214. – P. 436–444.

22. Cubberly W. H. Properties and selection – nonferrous alloys and pure metals. – ASM Metals handbook. V. 2. – ASM International, 1979. – 3470 p.

23. Livshits B.G., Kraposhin V.S., Linetsky, Ya.L., Fizicheskie svoistva metallov i splavov [Physical properties of metals and alloys], Moscow: Metallurgiya, 1980.

24. Angular dependence of sputtering for nickel in ferro- and paramagnetic states / D. A. Konov, A. S. Mosunov, G. V. Adamov et al. // Vacuum. – 2002. – P. 47–53.


Review

For citations:


Abdulmenova E.V., Vaulina O.Yu., Kulkov S.N. Structure and properties of iron-nickel invar sintered alloys. Voprosy Materialovedeniya. 2019;(3(99)):7-13. (In Russ.) https://doi.org/10.22349/1994-6716-2019-99-3-07-13

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ISSN 1994-6716 (Print)