Preview

Voprosy Materialovedeniya

Advanced search
Open Access Open Access  Restricted Access Subscription Access

Tribotechnical properties of ultra-high molecular weight polyethylene filled with sulfur, diphenylguanidine and 2-mercaptobenzothiazole

https://doi.org/10.22349/1994-6716-2019-99-3-91-98

Abstract

The paper studies tribotechnical properties, hardness and density of composites based on ultra-high molecular weight polyethylene (UHMWPE) filled with sulfur, diphenylguanidine (DFG) and 2-
mercaptobenzothiazole (MBT) and their mixtures. It has been established that the introduction of selected fillers has practically no effect on hardness and density of the composites, but leads to a significant (by 2–3 times) increase in the wear resistance of materials. Using electron microscopy, it has been established that secondary structures are formed in composites containing MBT that protect the surface layer of the material from wear. Using IR spectroscopy, it was established that tribochemical reactions occur during the wear of composites with the formation of hydroxyl and carbonyl groups. The developed materials UHMWPE / MBT and UHMWPE / FGD / MBT have high wear resistance and can be used as materials for tribological purposes.

About the Authors

S. N. Danilova
Ammosov North-Eastern Federal University
Russian Federation
48 Kulakovsky St, 677000 Republic of Sakha (Yakutia), Yakutsk, Russian Federation



A. A. Dyakonov
Ammosov North-Eastern Federal University
Russian Federation
48 Kulakovsky St, 677000 Republic of Sakha (Yakutia), Yakutsk, Russian Federation



A. P. Vasiliev
Ammosov North-Eastern Federal University
Russian Federation
48 Kulakovsky St, 677000 Republic of Sakha (Yakutia), Yakutsk, Russian Federation


Y. S. Gerasimova
Ammosov North-Eastern Federal University
Russian Federation
48 Kulakovsky St, 677000 Republic of Sakha (Yakutia), Yakutsk, Russian Federation


A. A. Okhlopkova
Ammosov North-Eastern Federal University, Institute of Oil and Gas Problems, Siberian Branch of the RAS
Russian Federation

Dr Sc. (Eng)

48 Kulakovsky St, 677000 Republic of Sakha (Yakutia), Yakutsk, Russian Federation 

20 Avtodorozhnaya St, 677007 Republic of Sakha (Yakutia), Yakutsk, Russian Federation



S. A. Sleptsova
Ammosov North-Eastern Federal University
Russian Federation
Cand Sc. (Eng)

48 Kulakovsky St, 677000 Republic of Sakha (Yakutia), Yakutsk, Russian Federation


References

1. Kurdi A., Chang L., Recent Advances in High Performance Polymers: Tribological Aspects, Lubricants, 2019, V. 7, No 1, p. 2.

2. Galibeev S.S., Khayrullin R.Z., Arkhireev V.P., Sverkhvysokomolekulyarny polietilen. Tendentsii i perspektivy [Ultra-high molecular weight polyethylene. Trends and prospects], Vestnik Kazanskogo tekhnologicheskogo universiteta, 2008, No 2, pp. 50–55.

3. Buznik V.M., Kablov E.N., Sostoyanie i perspektivy arkticheskogo materialovedeniya [Condition and perspectives of the Arctic materials science], Vestnik Rossijskoj akademii nauk, 2017, V. 87, No 9, pp. 827–839.

4. Panin S.V., Kornienko L.A., Vannasri S., Ivanova L.R., Shilko S.V., Sravnitelny analiz vliyaniya nano- i mikronapolnitelei okislennogo Al na friktsionno-mekhanicheskie svoistva SVMPE [Comparative Analysis of the Influence of Nano- and Microfillers of Oxidized Al on the Frictional-Mechanical Characteristics of UHMWPE], Trenie i iznos, 2010, V. 31, No 5, pp. 492–499.

5. Okhlopkova A.A., Nikiforov L.A., Okhlopkova T.A., Borisova R.V., Polymer Nanocomposites Exploited Under the Arctic Conditions, KnE Materials Science, 2016, V. 1, No 1, pp. 122–128.

6. Chukov D.I., Stepashkin A.A., Maksimkin A.V., Tcherdyntsev V.V., Kaloshkin S.D., Kuskov K.V., Bugakov V.I., Investigation of structure, mechanical and tribological properties of short carbon fiber reinforced UHMWPE-matrix composites, Composites Part B: Engineering, 2015, V. 76, pp. 79–88.

7. Borisova R.V., Spiridonov A.M., Okhlopkova T.A., Nikiforov L.A., Golikov A.N., Shadrinov N.V., Okhlopkova A.A., Bromination of UHMWPE surface as a method of changing adhesion to nanoparticles, Materials Today Communications, 2018, V. 14, pp. 65–71.

8. Kakhramanov N.T., Osipchik V.S., Gasumova G.Sh., Gadzhieva R.Sh., Iznosostoikie polimernye materialy: Struktura i svojstva [Wearproof polymeric materials: Structure and properties]. Plasticheskie massy, 2017, No 11–12, pp. 8–15.

9. Wang H., Xu L., Zhang M.X., Li R., Xing Z., Hu J.T., More wear-resistant and ductile UHMWPE composite prepared by the addition of radiation crosslinked UHMWPE powder, Journal of Applied Polymer Science, 2017, V. 134, No 13, DOI: 10.1002/app.44643.

10. Doshi B., Ward J.S., Oral E., Muratoglu O.K., Fatigue toughness of irradiated vitamin E/UHMWPE blends, Journal of Orthopedic Research, 2016, V. 34, No 9, pp. 1514–1520.

11. Dogadkin B.A., Dontsov A.A., Vzaimodeistvie polietilena s seroi v prisutstvii merkapto-benzotiazola i tetrametiltiuramdisulfida [Reaction of polyethylene with sulfur in the presence of mercaptoben-zothiazole and tetramethylthiuram disulfide], Vysokomolekulyarnye Soedineniya, 1963, No 1, pp. 1107–1117.

12. Tarasevich B.N., IK spektry osnovnykh klassov organicheskih soedinenii [The IR spectra of the major classes of organic compounds], Moscow: MGU (Moscow State University), 2012, p. 54.

13. Gu Y., Fei X., Lan Y., Shi B., Zhang B., Jia G., Synthesis, crystal structure and spectral properties of thiazole orange derivative, Chalcogenide Letters, 2010, V. 7, No 5, pp. 299–306.


Review

For citations:


Danilova S.N., Dyakonov A.A., Vasiliev A.P., Gerasimova Y.S., Okhlopkova A.A., Sleptsova S.A. Tribotechnical properties of ultra-high molecular weight polyethylene filled with sulfur, diphenylguanidine and 2-mercaptobenzothiazole. Voprosy Materialovedeniya. 2019;(3(99)):91-98. (In Russ.) https://doi.org/10.22349/1994-6716-2019-99-3-91-98

Views: 438


ISSN 1994-6716 (Print)