

Specific features of ruthenium influence on corrosion characteristics of different titanium alloys
https://doi.org/10.22349/1994-6716-2021-107-3-51-62
Abstract
This article discusses the results of corrosion tests and microstructural studies of forgings from various titanium alloys modified with ruthenium, of systems Ti–Al–Zr + 0.15% Ru, Ti–Al–V–Mo + 0.15% Ru, Ti–Al–V–Cr–Fe–Mo + 0.15% Ru and similar systems of basic compositions. On the basis of the performed complex of studies, the influence of the amount of the β-phase on the local content of ruthenium and, as a consequence, on the effect of cathodic protection in general was analyzed.
About the Authors
A. S. OryshchenkoRussian Federation
Corr. Member of the RAS
49 Shpalernaya St, 191015 St Petersburg
V. P. Leonov
Russian Federation
Dr Sc. (Eng)
49 Shpalernaya St, 191015 St Petersburg
E. V. Chudakov
Russian Federation
Cand Sc. (Eng)
49 Shpalernaya St, 191015 St Petersburg
Yu. Yu. Malinkina
Russian Federation
Cand Sc. (Eng)
49 Shpalernaya St, 191015 St Petersburg
References
1. Gorynin, I.V., Chechulin, B.B., Titan v mashinostroenii [Titanium in mechanical engineering], Moscow: Mashinostroenie, 1990.
2. Gorynin, I.V., Ushkov, S.S., Khatuntsev, A.N., Loshakova, N.I., Titanovye splavy dlya morskoy tekhniki [Titanium alloys for marine engineering], St. Petersburg: Politekhnika, 2007.
3. Ushkov, S.S., Podvodnaya lodka pr. 661 – pervaya v mire tselnotitanovaya submarina [Project 661 submarine – the world’s first all-titanium submarine], St Petersburg: CRISM “Prometey”, 2009, V. 1.
4. Grauman, J., Titanium and titanium alloy environmental behavior aspects for application to offshore oil & gas production (originally presented at a seminar “Titanium risers and flowlines”), Trondheim, 1999.
5. Chechulin, B.B., Parogeneratory – borba za resurs [Steam generators – the struggle for a resource], St Petersburg: CRISM “Prometey”, 2009, V. 1.
6. Bakhmetiev, A.M., Sandler, N.G., Bylov, I.A., Baklanov, A.V., Kashka, M.M., Filimoshkin, S.V., Analiz vozmozhnykh prichin i mekhanizmov otkazov trubnykh sistem parogeneratorov atomnykh sudov [Analysis of possible causes and failure mechanisms of pipe systems of steam generators of nuclear vessels], Arktika: ekologiya i ekonomika, 2013, No 3 (11), pp. 97–101.
7. Kashka, M.M., Mantula, N.V., Ponomarenko, A.V., Opyt i perspektivy ekspluatatsii v Arktike atomnogo ledokolnogo flota Rossii [Experience and prospects of operation in the Arctic of the Russian nuclear icebreaker fleet], Arktika: ekologiya i ekonomika, 2012, No 3 (7), pp. 84–91.
8. Tomashov, N.D., Titan i korrozionno-stoykie splavy na ego osnove [Titanium and corrosionresistant alloys based on it], Moscow: Metallurgiya, 1985.
9. URL: https://www.metaltorg.ru/pricelist/?type=all (reference date 15/01/2021)
10. Leonov, V.P., Chudakov, E.V., Malinkina, Yu.Yu., The influence of micro additives of ruthenium on the structure, corrosive-mechanical strength and fractography of destruction of pseudo-alphatitanium alloys, Inorganic Materials: Applied Research, 2017, V. 8, No 4, pp. 556–565.
11. Ilyin, A.A., Kolachev, B.A., Polkin, I.S., Titanovye splavy. Sostav. Struktura. Svoystva [Titanium alloys. Structure. Structure. Properties]: directory, Moscow: VILS-MATI, 2009.
12. Schutz, R.W., Minor ruthenium additions produce cost effective corrosion resistant commercial titanium alloys, Platinium metals review, 1996, V. 40, No 2, pp. 54–61.
13. Scherbinin, V.F., Leonov, V.P., Malinkina, Yu.Yu., Increase in corrosion resistance of titanium alloy in concentrated aqueous solutions of chlorides at high temperatures, Inorganic Materials: Applied Research, 2013, V. 4, Issue 6, pp. 537–541.
14. Leonov, V.P., Chudakov, E.V., Malinkina, Yu.Yu., Tretyakova, N.V., Petrov, S.N., Tsemenko, A.V., Vasilieva, E.A., Issledovanie osobennostey raspredeleniya ruteniya v titanovykh α-, psevdo-α- i psevdo-β splavakh i vliyanie ego na korrozionnuyu stoykost [Study of the features of the distribution of ruthenium in titanium α-, pseudo-α- and pseudo-β-alloys and its effect on corrosion resistance], Voprosy Materialovedeniya, 2020, No 3 (103), pp. 39–52.
15. Leonov, V.P., Chudakov, E.V., Malinkina, Yu.Yu., Vliyanie mikrodobavok ruteniya na strukturu, korrozionno-mekhanicheskuyu prochnost i fraktografiyu razrusheniya psevdo-β-titanovykh splavov [Influence of microadditives of ruthenium on the structure, corrosion-mechanical strength and fractography of the destruction of pseudo-β-titanium alloys], Materialovedenie, 2017, No 1, pp. 3–11.
16. Leonov, V.P., Chudakov, E.V., Malinkina, Yu.Yu., Vliyanie ruteniya na strukturu, korrozionno-mekhanicheskie svoystva i ustalostnye kharakteristiki alfa-titanovykh splavov v korrozionnoy srede [Effect of ruthenium on the structure, corrosive-mechanical properties and fatigue characteristics of alpha-titanium alloys in a corrosive environment], Voprosy Materialovedeniya, 2016, No 4, pp. 109–119.
17. Malinkina, Yu.Yu., Ispolzovanie ruteniya dlya povysheniya korrozionnoy stoykosti v agressivnykh sredakh promyshlennykh splavov titana [The use of ruthenium to improve corrosion resistance in corrosive environments of industrial titanium alloys], Voprosy Materialovedeniya, 2011, No 1 (65), pp. 162–166.
Review
For citations:
Oryshchenko A.S., Leonov V.P., Chudakov E.V., Malinkina Yu.Yu. Specific features of ruthenium influence on corrosion characteristics of different titanium alloys. Voprosy Materialovedeniya. 2021;(3(107)):51-62. (In Russ.) https://doi.org/10.22349/1994-6716-2021-107-3-51-62