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Application of carbon nanotubes produced by CVD-method for supercapacitor with LiPF6-based electrolyte
https://doi.org/10.22349/1994-6716-2022-109-1-64-76
Abstract
The paper studies carbon nanotubes (CNTs) synthesized by chemical vapor deposition (CVD) method on Fe-0.7Co/2.1Al2O3, Fe-Co/2.1Al2O3, and Co-Mo/Al2O3-MgO catalysts for supercapacitor electrodes with LiPF6-based electrolyte. It was found that the specific capacitance of 150–200 F/g for electrodes made of a mixture of carbon materials and graphite depends significantly on the conditions of creating intergranular contacts between graphite particles and CNTs that form a system of vacancies for ion introduction, in which reversible intercalation of PF6--anions occurs with minimal difficulties.
Supporting agencies: The study was carried out with the financial support of the Russian Foundation for Basic Research within the framework of the scientific project No 18-53-00032 Bel_a.
About the Authors
А. V. Shchegolkov
Tambov State Technical University
Russian Federation
Russian Federation
Cand Sc. (Eng)
106 Sovetskaya St, 392000 Tambov
М. S. Lipkin
South-Russian State Polytechnic University named after M.I. Platov
Russian Federation
Russian Federation
Dr Sc (Eng)
132 St Prosveshcheniya, Novocherkassk, 346428 Rostov region
А. V. Shchegolkov
Tambov State Technical University; South-Russian State Polytechnic University named after M.I. Platov
Russian Federation
Russian Federation
106 Sovetskaya St, 392000 Tambov
132 St Prosveshcheniya, Novocherkassk, 346428 Rostov region
А. Semenkova
South-Russian State Polytechnic University named after M.I. Platov
Russian Federation
Russian Federation
132 St Prosveshcheniya, Novocherkassk, 346428 Rostov region
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Review
For citations:
Shchegolkov А.V., Lipkin М.S., Shchegolkov А.V., Semenkova А. Application of carbon nanotubes produced by CVD-method for supercapacitor with LiPF6-based electrolyte. Voprosy Materialovedeniya. 2022;(1(109)):64-76. (In Russ.) https://doi.org/10.22349/1994-6716-2022-109-1-64-76
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