

Anode behavior and oxidation of Zn22Al alloy doped with scandium
https://doi.org/10.22349/1994-6716-2023-114-2-147-154
Abstract
The article contains the results of potentiodynamic and thermogravimetric research of anode behavior and oxidation of Zn22Al alloy, doped with scandium, in various media. The anode, kinetic and energy characteristics of alloys in isothermal conditions have been established. Doping of the Zn22Al alloy with scandium in an amount of 0.1 to 1.0 wt. % contributes to the increase of its anodic resistance to oxidation. The rate of oxidation and corrosion of alloys doped (0.01–0.1%) with scandium is 1.5–3 times lower than that of the Zn22Al alloy. Alloy oxidation products consist of a mixture of protective films ZnO, Sc2O3, ZnAl2O4 and Al2O3·Sc2O3.
About the Authors
M. M. MirmukhamedovTajikistan
299/2, St Aini, 734063 Dushanbe
U. R. Jobirov
Tajikistan
299/2, St Aini, 734063 Dushanbe
I. N. Ganiev
Tajikistan
Dr. Sc. (Chem)
299/2, St Aini, 734063 Dushanbe
Z. R. Obidov
Tajikistan
Dr. Sc. (Chem)
299/2, St Aini, 734063 Dushanbe
References
1. Кеchin , V.А., Lyblinsk y, Е.Y., Tsinkovye splavy [Zinc alloys], Мoscow: Metallurgiya, 1986.
2. Vitkin , А.I., Теindl, I.I., Metallicheskie pokritiya listovoy i polosovoy stali [Metal coverings of a sheet and strip steel], Мoscow: Metallurgiya, 1971.
3. Lin , K.L., Yang, C.F., Lee, J.T., Correlation of microstructure with corrosion and electrochemical behaviours of the bach-type hot-dip Al-Zn coatings. Part 1: Zn and 5% Al-Zn coatings, Corrosion, 1991, V. 47, No 4, pp. 9–13.
4. Lin, K.L., Yang, C.F., Lee, J.T., Correlation of microstructure with corrosion and electrochemical behaviours of the bach-type hot-dip Al-Zn coatings. Part 2: 55% Al-Zn coatings, Corrosion, 1991, V. 47, No 4, pp. 17–30.
5. Mazilkin , A.A., Straumal, B.B., Borodachenkova , M.V., Valiev, R.Z., Kogtenkova , O.A., Baretzky, B., Gradual softening of Al-Zn alloys during high-pressure torsion, Materials Letters, 2012, V. 84, pp. 63–65.
6. Amini, R.N., Irani, M., Ganiev, I.N., Obidov, Z.R., Galfan I and Galfan II Doped with Calcium, Corrosion Resistant Alloys, Oriental Journal оf Chemistry, 2014, V. 30, No 3, pp. 969–973.
7. Obidov, Z.R., Effect of pH on the Anodic Behavior of Beryllium and Magnesium Doped Alloy Zn55Al, Russian Journal of Applied Chemistry, 2015, V. 88, No 9, pp. 1451–1457.
8. Uesugi, T., Takigawa , Y., Kawasaki, M., Higashi, K., Achieving room-temperature superplasticity in an ultrafin-grainer Zn-22% Al alloy, Letters on materials, 2015, No 5 (3), pp. 269–275.
9. Obidov, Z.R., Anodic Behavior and Oxidation of Strontium-Doped Zn5Al and Zn55Al Alloys, Protection of Metals and Physical Chemistry of Surfaces, 2012, V. 48, No 3, pp. 352–355.
10. Maniram, S.G., Singh , G.M., Dehiya , S., Sharma , N.C., Effect of fly ash articles on the mechanical properties of Zn-22% Al alloy via stir casting method, IOSR Journal of Mechanical and Civil Engineering, 2013, V. 10, No 2, pp. 39–42.
11. Obidov, Z.R., Thermophysical Properties and Thermodynamic Functions of the Beryllium, Magnesium and Praseodymium Alloyed Zn-55Al Alloy, High Temperature, 2017, V. 55, N 1, pp. 150–153.
12. Kolotyrkin , Y.M., Metall i korroziya [Metal and Corrosion], Moscow: Metallurgiya, 1985. – 88 p.
Review
For citations:
Mirmukhamedov M.M., Jobirov U.R., Ganiev I.N., Obidov Z.R. Anode behavior and oxidation of Zn22Al alloy doped with scandium. Voprosy Materialovedeniya. 2023;(2(114)):147-154. (In Russ.) https://doi.org/10.22349/1994-6716-2023-114-2-147-154