

Structural features of composite electrochemical coatings nickel – diamond
https://doi.org/10.22349/1994-6716-2024-118-2-55-61
Abstract
The paper studies the structure of nickel-diamond composite electrochemical coatings obtained from the suspension electrolyte with ASM 7/5 powder. When the content of diamond powder in the electrolyte is 10 g/l, coatings are deposited with a uniform distribution of the reinforcing phase and a diamond volume fraction of up to 20%. Studies of the structure of the nickel coating matrix have revealed that, in comparison with standard galvanic nickel, which has a pronounced texture, the composite coating matrix has a finely dispersed structure with random grain orientation. Comparative measurements of nanohardness made it possible to record the strengthening of composite coatings matrix compared to galvanic nickel. Along with the high hardness of the reinforcing component and the relatively large particle size, this determines the high microhardness of the composite coating, which averages 860 HV.
Keywords
About the Author
A. V. KrasikovRussian Federation
Cand Sc. (Chem).
49 Shpalernaya St, 191015 St Petersburg
References
1. Huang, Ch.A., Yang, Sh.W., Shen, Ch.H., Cheng, K.Ch., Wang, H., Lai, P.L., Fabrication and evaluation of electroplated Ni – diamond and Ni – B-diamond milling tools with a high density of diamond particles, The International Journal of Advanced Manufacturing Technology, 2019, V. 104, pp. 2981–2989.
2. Yaskelchik, V.V., Zharsky, I.M., Burkat, G.K., Chernik, A.A., Mikhedova, E.V., Poluchenie i svoistva mednykh pokryty iz tsitratnogo elektrolita v prisutstvii ultradispersnykh almazov [Preparation and properties of copper coatings from citrate electrolyte in the presence of ultrafine diamonds], Izvestiya SPbGTI (TU), 2015, No 28, pp. 25–28.
3. Isaev, A.V., Zhirnova, T.A., Mikhalenko, M.G., Isaev, V.V., Bakaev, V.V., Vliyanie ultradispersnykh almazov na katodnoe osazhdenie serebra [The effect of ultrafine diamonds on the cathodic deposition of silver], Trudy Nizhegorodskogo gosudarstvennogo tekhnicheskogo universiteta imeni R.E. Alekseeva, 2014, No 2 (104), pp. 231–240.
4. Kuzmar, I.I., Vakulchik, V.A., Kushner, L.K., Khmyl, A.A., Optimizatsiya uslovy elektroosazhdeniya kompozitsionnykh pokryty olovo – ultradispersny almaz [Optimization of electrodeposition conditions of tin – ultrafine diamond composite coatings], Doklady BGUIR, 2011, No 6 (60), pp. 34–38.
5. Galevsky, G.V., Rudneva, V.V., Garbuzova, A.K., Elektroosazhdenie, struktura i svoistva kompozitsionnogo pokrytiya nikel – karbid titana [Electrodeposition, structure and properties of a composite coating of nickel – titanium carbide], Materialovedenie. Energetika, 2015, No 1 (214), pp. 154–164.
6. Wang, Sh.-Ch., Wei, W.-Ch. J., Kinetics of electroplating process of nanosized ceramic particle/Ni composite, Materials Chemistry and Physics, 2003, V. 78, pp. 574–580.
7. Fink, C.G., Prince, J.D., The codeposition of copper and graphite, Trans. Am. Electrochem. Soc., 1928, V. 54, pp. 315–321.
8. Krasikov, A.V., Agafonov, D.V., Markov, M.A., Belyakov, A.N., Kravchenko, I.N., Galinovsky, A.L., Kuznetsov, Yu.A., Electrodeposition of Ni–SiC composite coating from a vibration-stabilized electrolyte-suspension, Russian Metallurgy (Metally), 2023, V. 2023, No 6, pp. 796–802.
9. Krasikov, A .V., Markov, M. A., Krasikov, V.L., Kravchenko, I. N., Staritsyn ,M.V., Bykova, A. D., Belyakov, A. N., Influence of vibration parameters during electrodeposition of Ni–SiC composite coatings from a vibration stabilized suspension, Journal of machinery manufacture and reliability, 2022, V. 51, No 4, pp. 300–305.
10. Krasikov, A.V., Krasikov, V.L., Markov, M.A., Kravchenko, I.N., Galinovsky, A.L., Belyakov, A.N., Staritsyn, M.V., Bykova, A.D., Influence of vibration parameters on the composition of an electrochemical nickel-submicron silicon carbide composite coating, Russian Metallurgy (Metally), 2023, V. 2023, No 6, pp. 803–808.
Review
For citations:
Krasikov A.V. Structural features of composite electrochemical coatings nickel – diamond. Voprosy Materialovedeniya. 2024;(2(118)):55-61. (In Russ.) https://doi.org/10.22349/1994-6716-2024-118-2-55-61