Preview

Voprosy Materialovedeniya

Advanced search
Open Access Open Access  Restricted Access Subscription Access

Thermal characteristics and physical and mechanical properties of aromatic polyamidines and materials based on them

https://doi.org/10.22349/1994-6716-2018-96-4-151-159

Abstract

Aromatic polyamidines were synthesized by polycondensation of equimolecular amounts of bisimidoyl chlorides with diamines in organic solvents. The obtained polymers are dissolved with organic solvents (N, N'-dimethylacetamide, N-methyl-2-pyrrolidone, etc.), and characterized by a large interval between the temperature of plastic deformation and heat resistance, that is a good possibility of processing polyamidine products with new industrial methods.

About the Authors

D. M. Mognonov
Baikal Institute for Nature Management, Siberian Branch of the Russian Academy of Sciences
Russian Federation

Dr Sc (Chem)

6 Sakhyanovoy St, 670047, Ulan-Ude, Republic of Buriatiya



Yu. V. Tonevitsky
Buriatsky State University
Russian Federation

Cand Sc (Chem)

24a Smolina St, 670000 Ulan-Ude, Republic of Buriatiya



O. Zh. Ayurova
Baikal Institute for Nature Management, Siberian Branch of the Russian Academy of Sciences
Russian Federation

Cand Sc (Eng)

6 Sakhyanovoy St, 670047, Ulan-Ude, Republic of Buriatiya



O. V. Ilyina
Baikal Institute for Nature Management, Siberian Branch of the Russian Academy of Sciences
Russian Federation

Cand Sc (Eng)

6 Sakhyanovoy St, 670047, Ulan-Ude, Republic of Buriatiya



V. N. Kornopoltsev
Baikal Institute for Nature Management, Siberian Branch of the Russian Academy of Sciences
Russian Federation

Cand Sc (Eng) 

6 Sakhyanovoy St, 670047, Ulan-Ude, Republic of Buriatiya



References

1. Patai, S., The Chemistry of amidines and imidates, London; New York; Sydney; Toronto: John Wiley and Sons, 1975.

2. Granik, V.G., Uspekhi khimii amidinov [Advances in the chemistry of amidines], Uspekhi Khimii, 1983, V. 52, No 4, pp. 669–702.

3. Bohme, F., Kunert, C., Klinger, C., Komber, H., Structural influences on the properties of aromatic polyamidines, Macromol. Symp., 1998, V. 128, pp. 183–193.

4. Kurita, K., Kusayama, Y., Iwakura, Y., Polyadditions of bisketenimines. I. Syntesis of polyamidines from bisketenimines and diamines, J. Polym. Sci.: Polym. Chem. Ed., 1977, V. 15, No 9, p. 2163.

5. Ogata, S., Kakimoto, M., Imai, Y., Direct synthesis of new aromatic polyamidines from aromatic diamines and benzoic acids by using poly(trimethylsilylphosphate), Macromol. Chem., Rapid Commun., 1985, V. 6, No 12, p. 835.

6. Tonevitsky, Yu.V., Mognonov, D.M., Sanzhizhapov, D.B., Doroshenko, Yu.E., Khakhinov, V.V., Samsonov, V.G., Batoyeva, S.O., N-fenilzameshchennye polibenzimidazoly na osnove aromaticheskikh diaminov i imidoilkhloridov mono- i dikarbonovykh kislot [N-phenyl-substituted polybenzimidazoles based on aromatic diamines and imidoyl chlorides of mono- and dicarboxylic acids], Polym. Sci., Ser. B., 2000, V. 42, No 5–6, pp. 146–150.

7. Toktonov, A.V., Mognonov, D.M., Mazurevskaya, Zh.P., Batoyeva, S.O., Sintez poliamidinov na osnove aromaticheskikh bisimidoilkhloridov v rastvore [Synthesis of polyamidines based on aromatic bisimidoyl chlorides in solution], Polym. Sci. Ser. A, 2006, V. 48, No 1, p. 1–10.

8. Korshak, V.V., Termostoikie polimery [Heat-resistant polymers], Moscow: Nauka, 1969.

9. Korshak V.V. Khimicheskoe stroenie i temperaturnye kharakteristiki polimerov [Chemical structure and temperature characteristics ofpolymers], Moscow: Nauka, 1970, p. 419.

10. Matveev, Yu.I., Askadsky, A.A., Zhuravleva, I.V., Slonimsky, G.L., Kors h a k, V.V., O vliyanii khimicheskogo stroeniya polimerov na ikh termostoikost [On the influence of the chemical structure of polymers on their thermal stability], Polym. Sci.,1981, V. 23, No 9, p. 2013.

11. Matveev, Yu.I., Askadsky, A.A., Khimicheskoe stroenie i fizicheskie svoistva polimerov [Chemical structure and physical properties of polymers], Moscow: Khimiya, 1983.

12. Frazer, A.G., Vysokotermostoikie polimery [High temperature resistant polymer], Pravednikov, A.N., (Ed.), Moscow: Khimiya, 1971.

13. Alperin, V.I., Korolkov, N.V., Motavkin, A.V., Roginsky, S.L., Teleshov, V.A., Konstruktsionnye stekloplastiki [Structural fiberglass], Moscow: Khimiya, 1979.

14. Sokolov, L.B., Gerasimov, V.D., Savinov, V.M., Beliakov, V.K., Termostoikie aromaticheskie poliamidy [Heat-resistant aromatic polyamides], Moscow: Khimiya, 1975.

15. Mognonov, D.M., Sintez termostoikikh poligeteroarilenov s benzimidazolnymi tsiklami [Synthesis of heat-resistant polyheteroarylenes with benzimidazole cycles]: Thesis for the degree of Dr. Sc (Chem.), Irkutsk, 2002.

16. Grigorieva, M.N., Mognonov, D.M., Tonevitsky, Yu.V., Stelmakh, S.A., Ochirov, O.S., Aromaticheskie polibenzimidazoly na osnove 4.4'-difenilmetandiizotsianata i bis-(arilen)gidroksamovykh kislot [Aromatic polybenzimidazoles on the bases of 4,4'-diphenylmethane diisocyanate and bis(arylene)hydroxamic acids], Polym. Sci., Ser. B, V. 60, No 1, pp. 16–19.

17. Rusanov, A. L., Likhachev, D. Yu., Muller, K., Elektroliticheskie protonprovodyaschie membrany na osnove aromaticheskikh kondensatsionnykh polimerov [Electrolytic proton-conducting membranes based on aromatic condensation polymers], Uspekhi Khimii, 2009, V. 71, No 9, pp. 862–877.

18. Mognonov, D.M., Dashitsyrenova, M.S., Pinus, I.Yu., Mazurevskaya, Zh.P., Doroshenko, Yu. E., Yaroslavtsev, A.B., Thermodynamic characteristics of polyheteroarylene blends, Polym. Sci. Ser. A, 2010, V. 52, No 6, pp. 621–627.


Review

For citations:


Mognonov D.M., Tonevitsky Yu.V., Ayurova O.Zh., Ilyina O.V., Kornopoltsev V.N. Thermal characteristics and physical and mechanical properties of aromatic polyamidines and materials based on them. Voprosy Materialovedeniya. 2018;(4(96)):151-159. (In Russ.) https://doi.org/10.22349/1994-6716-2018-96-4-151-159

Views: 412


ISSN 1994-6716 (Print)