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Performance properties of Ni–W, Co–W and Ni–P–W coatings hardened by heat treatment
https://doi.org/10.22349/1994-6716-2025-123-3-80-88
Abstract
The article presents the results of a comprehensive study of the main performance properties of tungsten-containing galvanic coatings Ni–W, Co–W and Ni–P–W, hardened by heat treatment. It is shown that for binary alloys, heat treatment at 600°C is optimal, which allows achieving maximum wear resistance. For the ternary system, it is advisable to use annealing at 350°C. As a result of annealing, all the studied coatings have high adhesion. It is concluded that to ensure wear resistance of machine parts, it is advisable to use Co–W coatings, and for protection against wear and corrosion in salt water, the most acceptable coating is Ni–P–W.
About the Authors
A. V. Krasikov
NRC “Kurchatov Institute” – CRISM “Prometey”
Russian Federation
Russian Federation
Cand Sc. (Eng)
49 Shpalernaya St, 191015 St Petersburg
M. V. Merkulova
NRC “Kurchatov Institute” – CRISM “Prometey”
Russian Federation
Russian Federation
49 Shpalernaya St, 191015 St Petersburg
M. E. Goshkoderya
NRC “Kurchatov Institute” – CRISM “Prometey”
Russian Federation
Russian Federation
49 Shpalernaya St, 191015 St Petersburg
References
1. Brenner, A., Burkhead, P., Seegmiller, E., Electrodeposition of tungsten alloys containing iron, nickel and cobalt, Journal of research of the national bureau of standards, 1947, V. 39, pp. 351–383.
2. Golts, L.N., Kharlamov, V.N., Elektroliticheskoe osazhdenie splavov volframa, nikelya i medi iz vodnykh rastvorov [Electrolytic deposition of tungsten, nickel, and copper alloys from aqueous solutions], Zhurnal prikladnoi khimii. 1936, V. 9, pp. 640–652.
3. Vasko, A.T., Elektrokhimiya volframa [Electrochemistry of tungsten], Kiev: Tekhnika, 1969.
4. Tsyntsaru, N., et al., Modern Trends in Tungsten Alloys Electrodeposition with Iron Group Metals, Surface Engineering and Applied Electrochemistry, 2012, V. 48, No 6, pp. 491–520.
5. . Eliaz, N . , Gilead, E. , Induced Codeposition of Alloys of Tungsten, Molybdenum and Rhenium with Transition Metals, Modern Aspects of Electrochemistry, 2008, No 42, pp. 191–301.
6. . Yamasaki , T. , High-strength nanocrystalline Ni–W Alloys produced by electrodeposition, Mater. Phys. Mech., 2000, V. 1, pp. 127–132.
7. Donten, M., Bulk and surface composition, amorphous structure, and thermocrystallization of electrodeposited alloys of tungsten with iron, nickel, and cobalt, J. Solid State Electrochem., 1999, No 3, pp. 87–96.
8. Vasko, A.T., Elektrokhimiya molibdena i volframa [Electrochemistry of Molybdenum and Tungsten], Kiev: Naukova dumka, 1977.
9. He, F. , Yang , J. , Lei, T. , Gu, Ch. , Structure and Properties of Electrodeposited Fe–Ni–W Alloys with Different Levels of Tungsten Content: A Comparative Study, Appl. Surf. Sci., 2007, V. 253, Is. 18, pp. 7591–7598.
10. Tharamani, C.N., Beera, P., Jayaram, V., Begum, N.Sh., Studies on electrodeposition of Fe–W alloys for fuel cell applications, Applied Surface Science, 2006, V. 253, Is. 4, pp. 2031–2037.
11. Galikova, Z., Chovancova, M., Danielik, V., Properties of Ni–W alloy coatings on steel substrate, Chemical Papers, 2006, No 60 (5), pp. 353–359.
12. Chen, H., Ren, X., Zhang, X., Jinhui, L., Wear and Corrosion Properties of Crystalline Ni–W Alloy Coatings Prepared by Electrodeposition, Materials Science Forum, 2016, V. 849, pp. 671–676.
13. Hamid, Z.A., Electrodeposition of cobalt–tungsten alloys from acidic bath containing cationic surfactants, Materials Letters, 2003, No 57 (16–17), pp. 2558–2564.
14. Krasikov, A.V., Merkulova, M.V., Mikhailov, M.S., et al., Formation of a composite coating by crystallization of supersaturated solid solution in the Ni–W system, Transactions of the Indian institute of metals, 2024, V. 77, No 9, pp. 2901–2908.
15. Krasikov, A.V., Kastsova, A.G., Markov, M.A., et al., Electrochemical Synthesis of Amorphous Layers from a Nonequilibrium Co–W Alloy as a Precursor for Nanocomposite Coating Formation, Russian Metallurgy, 2022, V. 2022, No 6, pp. 666–673.
16. Krasikov, A. V. , Synthesis of Nanocomposite Coatings Based on Electrodeposited Amorphous Ni–P–W Layers, Inorganic Materials: Applied Research, 2020, V. 11, No 6, pp. 1359–1363.
17. Bera, P., Seenivasan, H., Rajam, K.S., Grips, W.V.K., XRD, FESEM and XPS studies on heat treated Co–W electrodeposits, Materials Letters, 2012, V. 76, pp. 103–105.
18. Krolikowski, A., Plonska, E., Ostrowski, A., et al. Effects of compositional and structural features on corrosion behavior of nickel-tungsten alloys, J. Solid State Electrochem., 2009, V. 13, pp. 263–275.
19. Cesiulis, H., Sinkeviciute, J., Bersirova, O., Ponthiaux, P. Tribocorrosion Testing of Self-Passivating Molybdenum and Tungsten Alloys Containing Cobalt and Iron, BALTTRIB 2009, Proceedings, 2009, pp. 253–258.
20. Hosseini, M. G. , Abdolmaleki, M. , Ebrahimzadesh, H. , Sadjadi, S. S. A. , Effect of 2-butyne-1,4-diol on the nanostructure and corrosion resistance properties of Electrodeposited Ni–W–B Coatings, Int. J. Electrochem. Sci., 2011, V. 6, pp. 1189–1205.
21. Chianpairot, A., Lothongkum, G., Schuh, A.C., Boonyongmaneerat, Y., Corrosion of nanocrystalline Ni–W alloys in alkaline and acidic 3.5 wt.% NaCl solutions, Corrosion Science, 2011, V. 53, pp. 1066–1071.
22. Gulyaev, A.P., Korrozionno-stoikie splavy tugoplavkikh metallov [Corrosion-resistant alloys of refractory metals], Moscow: Nauka, 1982.
23. Tharamani, C. N., Beera P., Jayaram, V., et al., Studies on electrodeposition of Fe–W alloys for fuel cell applications, Applied Surface Science, 2006, V. 253, Is. 4, pp. 2031–2037.
24. Younes, O., et al., Electroplating of Amorphous Thin Films of Tungsten/Nickel Alloys, Langmuir, 2001, V. 17 (26), pp. 8270–8275.
25. Younes, O., Gileadi, E., Electroplating of Ni/W Alloys I. Ammoniacal Citrate Baths, J. Electrochem. Soc., 2002, V. 149 (2), pp. 100–111.
26. Younes - Metzler, O. , Zhu, L. , Gileadi, E. , The anomalous codeposition of tungsten in the presence of nickel, Electrochimica Acta, 2003, No 48 (18), pp. 2551–2562.
Review
For citations:
Krasikov A.V., Merkulova M.V., Goshkoderya M.E. Performance properties of Ni–W, Co–W and Ni–P–W coatings hardened by heat treatment. Voprosy Materialovedeniya. 2025;(3(123)):80-88. (In Russ.) https://doi.org/10.22349/1994-6716-2025-123-3-80-88
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