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Influence of the nature of the inert carrier on the efficiency of microencapsulation of a corrosion and scale inhibitor

https://doi.org/10.22349/1994-6716-2025-123-3-145-155

Abstract

Microencapsulation of corrosion inhibitors allows increasing the efficiency of modification of polymer composite coatings, increasing their corrosion resistance over a long period. The selection of an inert carrier, which constitutes a solid base of a functional particle, remains an urgent task. The paper considers the features of solid carriers of functional additives, which are used to obtain microcapsules. The kinetics of release of an inhibitory agent was studied by a spectrophotometric method with the construction of a calibration graph. It was found that activated aluminum oxide showed the highest loading of the inhibitory agent and a longer release time among the considered carriers.

About the Authors

S. A. Sidorova
MIREA – Russian Technological University
Russian Federation

 78 Vernadsky Ave, 119454 Moscow 



S. A. Tyurina
MIREA – Russian Technological University
Russian Federation

Cand Sc. (Eng)

78 Vernadsky Ave, 119454 Moscow 



N. A. Rashutin
MIREA – Russian Technological University
Russian Federation

 78 Vernadsky Ave, 119454 Moscow 



V. L. Demin
MIREA – Russian Technological University; Frumkin Institute of Physical Chemistry and Electrochemistry
Russian Federation

Cand Sc. (Eng)

78 Vernadsky Ave, 119454 Moscow 

31/bldg 4 Leninsky Ave, 119071 Moscow 



V. A. Shchelkov
Frumkin Institute of Physical Chemistry and Electrochemistry
Russian Federation

Cand Sc. (Eng)

31/bldg 4 Leninsky Ave, 119071 Moscow 



References

1. R ashutin, N.A., Tyurina , S.A., Demin, V.L., Ustanovki dlya uskorennogo nakipeobrazovaniya [Plants for accelerated scale formation], Proceedings of the conference IPTIP RTU MIREA “Perspektivnye materialy i tekhnologii (PMT-2024)”, Moscow: MIREA, 2024, pp. 235–236. EDN CTEBPP

2. Schmitt, G., et al., Global needs for knowledge dissemination, research, and development in materials deterioration and corrosion control, World Corrosion Organization, 2009. URL: http://www.corrosion.org.cn/fszy/202304/P020230501743614591484.pdf (reference date 31/08/2025)

3. Tatarintsev, V.A., Osobennosti nakipeobrazovaniya v trubakh teploobmennykh apparatov [Features of scale formation in heat exchange apparatus pipes [Features of scale formation in heat exchanger pipes], Vestnik YuUrGU. Ser. Energetika, 2022, No 1, pp. 97–105. DOI: 10.14529/power220111

4. Obot, I.B., Under-Deposit Corrosion on Steel Pipeline Surfaces: Mechanism, Mitigation and Current Challenges, J. Bio. Tribo. Corros., 2021, V. 7, Issue 2, Art. 49. URL: https://doi.org/10.1007/s40735-021-00485-9

5. Bannyh , O. P., Osnovnye konstruktsii i teplovoi raschet teploobmennikov [Basic srructures and thermal calculation of heat exchangers], St Petersburg: SPbNIU ITMO, 2012, 42 p.

6. Galkovsky, V.A., Chupova , M.V., Analiz snizheniya koeffitsienta teploperedachi teploobmennykh apparatov vsledstvie zagryazneniya poverkhnosti [Analysis of the decrease in the heat transfer coefficient of heat exchange devices due to surface contamination], Naukovedenie, 2017, V. 9, No 2 (March–April). URL: http://naukovedenie.ru/PDF/41TVN217.pdf (reference date 31/08/2025).

7. Gnedenkov, S .V., Sinebryukhov, S . L ., Minaev, A. N., Mashtalyar, D.V., Gordienko, P. S., Vliyanie pokrytiy na intensivnost protsessov soleotlozheniya [Influence of coatings on the intensity of salt deposition processes], Issledovano v Rossii, V. 6, Moscow: MFTI, 2003, pp. 1780–1790. URL: http://web.archive.org/web/20040320051934/http://zhurnal.ape.relarn.ru/articles/2003/146.pdf (reference date 31/08/2025).

8. Ramezanzadeh, B., Moghadam, M.H.M., Shohani, N., Mahdavian , M., Effects of highly crystalline and conductive polyaniline / graphene oxide composites on the corrosion protection performance of a zinc-rich epoxy сoating, Chemical Engineering Journal, 2017, No 320, pp. 363–375. DOI: 10.1016/j.cej.2017.03.061. EDN: YXJCLP.

9. Sharifi , E. , Ranjbar, K h. , Dezincification assisted cracking of yellow brass tubes in a heat exchange, Engineering Failure Analysis, 2022, V. 136, p. 106200. URL: https://doi.org/10.1016/j.engfailanal.2022.106200

10. Li, H., Liu H., Wa ng G., Z ha ng X., Chen T., Yu Y., Yao H., Review on Erosion-wear and Protection of Heat Exchange Surface in Power Station Boilers, Journal of Chinese Society for Corrosion and Protection, 2023, V. 43, No 5, pp. 957–970.

11. Sa nder, J., et al., Korrosionsschutz durch Beschichtungen, Hannover: Vincentz Verlag, 2011.

12. Asad i, N., Nader i, R., Ma hd avia n, M., Doping of zinc cations in chemically modified hal-loysite nanotubes to improve protection function of an epoxy ester coating, Corros. Sci., 2019, No 151, pp. 69–80. DOI: 10.1016/j.corsci.2019.02.022. EDN: WAGAGG.

13. Stepin, S. N. , Tolstosheeva, S. I. , Svetlakov, A . P. , Protektornye tsinkonapolnen-nye gruntovki. Vliyanie komponentov na protivokorrozionnuyu effektivnost. Ch. 1 [Effect of components on anticorrosive efficiency. Part 1], Vestnik Kazanskogo tekhnologicheskogo universiteta, 2016, V. 19, No 9,pp. 122–128.

14. Drinberg, A.S., Itsko, E .F., Kalinskaya , T.V., Antikorrozionnye gruntovki [Anticorro-sion primers], St Petersburg NIPROINS LKM i PSOP, 2006.

15. Pavlovich, A.V., Vladenkov, V.V., Izyumsky, V.N., Zinc-filled anti-corrosion primers,Lakokrasochnaya promyshlennost, 2010, No 3, pp. 38–46.

16. A ndreeva , S.A., Tyurina , S.A., Dalskaya , G.Yu., Izuchenie kinetiki vysvobozhdeniya funktsionalnykh dobavok iz mikrokapsul [Study of the kinetics of functional additives release from microcap-sules], Proceedings of the conference “Perspektivnye materialy i tekhnologii (PMT-2023)”, A.N. Yu rasov ( Ed.), Moscow: MIREA, 2024, V. 1, pp. 319–325. EDN OHIDZS

17. Rashutin, N.A., Tyurina , S.A., Demin, V.L., Sidorova , S.A., Podkhody k izmeneni-yu zashchitnykh svoistv polimernykh pokrytiy pri ispolzovanii modifitsiruyushchikh dobavok [Approaches to changing the protective properties of polymer coatings using modifying additives], Butlerovskie soobsh-cheniya, 2023, V. 76, No 12, pp. 42–50. DOI 10.37952/ROI-jbc-01/23-76-12-42. EDN QUNLAS

18. Rashutin, N.A., Tyurina , S.A., Vliyanie funktsionalnykh dobavok na protsess nakipeobra-zovaniya zashchitnykh polimernykh pokrytiy [The effect of functional additives on the scale formation pro-cess of protective polymer coatings], Proceedings of the conference “Opticheskie tekhnologii, materialy i sis-temy”, Moscow: MIREA, 2022, pp. 311–314. EDN BPKSZX

19. Gnedenkov, S.V., Minaev, A.N., Lysenko, L.V., Shatalov, V.K., Shapkina , E.I.,Lysenko, S.L., Issledovanie nakipeobrazovaniya v perspektivnykh forsirovannykh teploobmennykh siste-makh [Study of scale formation in advanced forced heat exchange systems], Naukoemkie tekhnologii, 2013,V. 7, pp. 26–34.

20. Golovin, V.A., Shchelkov, V.A., Rashutin, N.A., Tyurina, S.A., Demin , V.L .,Mikrokapsulirovannye i aktivnye dobavki dlya povysheniya antinakipnykh svoistv polimernykh protivokor-rozionnykh pokrytiy [Microencapsulated and active additives for improving the anti-scale properties of poly-mer anti-corrosion coatings], Korroziya: zashchita materialov i metody issledovaniy, 2023, No 4, pp. 131–141.URL: https://doi.org/10.61852/2949-3412-2023-1-4-131-141

21. Golovin, V.A., Tyurina , S.A., Microencapsulation of corrosion inhibitors and active addi-tives for anticorrosive protective polymer coatings, International Journal of Corrosion and Scale Inhibition,2019, V. 8, No 2, pp. 179–198. DOI: 10.17675/2305-6894-2019-8-2-2. EDN VQWFAB

22. Bakhvalov, A .V. , Opredelenie soderzhaniya fosfonatov v tekhnologicheskoi vode kosven-nym kolorimetricheskim metodom s primeneniem dvukh graduirovochnykh zavisimostei [Determination of phosphonates in process water by an indirect colorimetric method using two calibration curves], Proble-my sovremennoy nauki i obrazovaniya, 2021, No 11 (168). URL: https://cyberleninka.ru/article/n/opredele-nie-soderzhaniya-fosfonatov-v-tehnologicheskoy-vode-kosvennym-kolorimetricheskim-metodom-s-prime-neniem-dvuh-graduirovochnyh (reference date 18/12/2024).

23. Sidorova, S.A., Dalskaya, G.Yu., Tyurina, S.A., Demenkov, A.S., Sakharov, M.V.,Issledovanie morfologii mikrokapsul, primenyaemykh dlya modifikatsii antikorrozionnykh polimernykh pokrytiy [Study of the morphology of microcapsules used for modifying anti-corrosion polymer coatings],Proceedings of the conference of IPTIP RTU MIREA “Perspektivnye materialy i tekhnologii (PMT-2024)”,Moscow: MIREA, 2024.


Review

For citations:


Sidorova S.A., Tyurina S.A., Rashutin N.A., Demin V.L., Shchelkov V.A. Influence of the nature of the inert carrier on the efficiency of microencapsulation of a corrosion and scale inhibitor. Voprosy Materialovedeniya. 2025;(3(123)):145-155. (In Russ.) https://doi.org/10.22349/1994-6716-2025-123-3-145-155

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ISSN 1994-6716 (Print)