Preview

Voprosy Materialovedeniya

Advanced search
Open Access Open Access  Restricted Access Subscription Access

Zinc-stearate modification of epoxy resins and carbon plastics based on them and its influence on the basic technological properties of the composition

https://doi.org/10.22349/1994-6716-2018-95-3-146-156

Abstract

The influence of the special modification of epoxy resins and polymer composites based on them on the basic technological properties of the composition is investigated. Modification is performed in order to reduce the opening damage. The most important technological properties of the initial epoxy composition and modified technological additives are studied and compared by standard methods (viscosimetry, thermoanalytical methods). A kinetic model of the curing process was created, the experimental production of samples from plastics filled with carbon long filler (impregnation under pressure, autoclave molding) and its non-destructive testing were carried out.

About the Authors

F. A. Nasonov
Moscow Aviation Institute; Sukhoi Company of Sukhoi Design Bureau
Russian Federation

4 Volokolamskoe shosse, 125993 Moscow; 23A St Polikarpova, 125264 Moscow



V. M. Aleksashin
Federal State Unitary Enterprise “All-Russian Scientific Research Institute of Aviation Materials” (FSUE VIAM)
Russian Federation

Cand Sc. (Eng)

17 Radio St, 105005 Moscow



D. A. Melnikov
Federal State Unitary Enterprise “All-Russian Scientific Research Institute of Aviation Materials” (FSUE VIAM)
Russian Federation
17 Radio St, 105005 Moscow


S. V. Bukharov
Moscow Aviation Institute
Russian Federation

Dr Sc (Eng)

4 Volokolamskoe shosse, 125993 Moscow

 



References

1. Kablov, E.N., Innovatsionnye razrabotki FGUP VIAM po realizatsii “Strategicheskikh napravleniy razvitiya materialov i tekhnologiy ikh pererabotki na period do 2030 goda” [Innovative developments FSUE VIAM on the implementation of “Strategic directions for the development of materials and technologies for their processing for the period until 2030”], Aviatsionnye materialy i tekhnologii, 2015, No 1, pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.

2. Kablov, E.N., Startsev, O.V., Fundamentalnye i prikladnye issledovaniya korrozii i stareniya materialov v klimaticheskikh usloviyakh [Fundamental and applied researches of corrosion and aging of materials in climatic conditions (review)], Aviatsionnye materialy i tekhnologii, 2015, No 4, pp. 38–52. DOI: 10.18577/2071-9140-2015-0-4-38-52.

3. Kablov, E.N., Startsev, V.O., Inozemtsev, A.A., Vlagonasyschenie konstruktivnopodobnykh elementov iz polimernykh kompozitsionnykh materialov v otkrytykh klimaticheskikh usloviyakh s nalozheniem termotsiklov [Moisture saturation of constructively similar elements from polymeric composite materials in open climatic conditions with superposition of thermal cycles], Aviatsionnye materialy i tekhnologii, 2017, No 2, pp. 56–68. DOI: 10.18577/2071-9140-2017-0-2-56-68.

4. Petrova, A.P., Lukina, N.F., Melnikov, D.A., Besednov, K.L., Pavliuk, B.F., Issledovanie svoistv otverzhdennykh kleevykh svyazuyuschikh [Investigation of the properties of cured adhesive binders], Proceedings of VIAM, No 201, Art. 06, URL: http://www.viam-works.ru (reference date 01.02.2018). DOI: 10.18577/2307-6046-2017-0-10-6-6.

5. Korotkov, S.N., Zhovner, B.A., Issledovanie metodom DSK antiadgezionnykh dobavok na vremya otverzhdeniya epoksidnykh svyazuyushchikh v protsesse pultruzii [Investigation by DSC of antiadhesive additives for the curing time of epoxybinders in the process of pultrusion], Plasticheskie massy, 1991, No 5, p. 46.

6. Nosov, K.S., Lapshina, E.M., Vliyanie tekhnologicheskoy smazki na reologicheskie i prochnostnye svoistva polimer-mineralnykh materialov, poluchennykh metodom plastformovaniya [The effect of technological lubrication on the rheological and strength properties of polymer-mineral materials obtained by the method of plastic molding], Proceedings POLIKOTRIB-2015, Gomel, 2015. p. 39.

7. Gadeev, A.S., Koltaev, N.V., Sultanov, A.I., Zaripov, T.F., Glazyrin, A.B., Basyrov, A.A., Modifitsiruyushchie dobavki dlia polimernykh kompozitsiy na osnove polietilena [Modifying additives for polymer compositions based on polyethylene], Nauka i obrazovanie segodnya, 2016, No 9, pp. 5–9.

8. Markov, V.A., Kandyrin, L.B., Markov, A.V., Vliyanie tekhnologicheskikh dobavok na elektricheskie kharakteristiki polietilenovykh kompozitov s tekhnicheskim uglerodom [The effect of technological additives on the electrical characteristics of polyethylene composites with technical carbon], Vestnik MITKhT, 2013, V. 8, No 6, pp. 103–106.

9. Niftaliev, S.I., Lygina, L.V., Peregudov, Yu.S., Prokofieva, L.A., Issledovanie reologicheskikh svoistv kompozitsiy na osnove PVKh [Investigation of rheological properties of PVC-based compositions], Vestnik VGUIT, 2014, No 2, pp. 132–134.

10. Kirillov, A. G., Latyshev, M. V., Ratnikov, A. S., Povyshenie iznosostoikosti tsilindra avtomobilnogo dvigatelya pri ispolzovanii tribologicheskikh sostavov [Increase of wear resistance of the cylinder of the automobile engine with the use of tribological compositions], Vestnik TTU im. M.S. Osimi, 2011, V. 3, No 3, pp. 43–47.

11. Chernin, I.Z., Smezov, F.M., Zherdev, Yu.V., Epoksidnye polimery i kompozitsii [Epoxy polymers and compositions], Moscow: Khimiya, 1982, pp. 6–32.

12. Plastiki konstruktsionnogo naznacheniya (reaktoplasty) [Plastics for structural purposes (thermosets)], Trostianskaya, E.B., (Ed.), Moscow: Khimiya, 1974, pp. 81–86.

13. Mikhenko, I.P., Tekhnologiya polufabrikatov polimernykh materialov [Technology of semifinished polymeric materials], St Petersburg:Nauchnye osnovy i tekhnologii, 2012, pp. 120–132.

14. Mikhailin, Yu.A., Konstruktsionnye polimernye kompozitsionnye materialy [Structural polymeric composite materials], St Petersburg: Nauchnye osnovy i tekhnologii, 2008, pp. 124–154.

15. Antiufeeva, N.V., Zhuravleva, P.L., Aleksashin, V.M., Kutsevich, K.E., Vliyanie stepeni otverzhdeniya svyazuyuschego na fiziko-mekhanicheskie svoistva ugleplastika i mikrostrukturu mezhfaznogo sloya uglerodnoe volokno/matritsa [Effectof the degree of curing of the binder on the physical and mechanical properties of CFRP and the microstructure of the interfacial layer of a carbon fiber/matrix], Klei. Germetiki. Tekhnologii, 2014, No 12, pp. 26–30.

16. Khabenko, A.V., Dolmatov, S.A., Optimizatsiya protsessov otverzhdeniya materialov na osnove poli-bis-maleinimidaminov s pomoschyu metoda DSK [Optimization of the processes of curing materials based on poly-bis-maleimineamides using the DSC method], Plasticheskie massy, 1987, No. 9, pp. 44–45.

17. Malysheva, G.V., Akhmetova, E.S., Shimina, Yu.Yu., Otsenka temperatur fazovykh perekhodov polimernykh svyazuyushchikh metodom differentsialno-skaniruyushchey kalorimetrii [Estimation of temperatures of phase transitionsof polymeric binders by differential scanning calorimetry method], Klei. Germetiki. Tekhnologii, 2014, No 6, pp. 29–33.

18. Antiufeeva, N.V., Aleksashin, V.M., Primenenie metodov termicheskogo analiza dlia opredeleniya pokazateley tekhnologicheskikh i ekspluatatsionnykh svoistv materialov [Application of thermal analysis methods to determine the indicators of technological and operational properties of materials], Vse materialy: Encyclopedic reference book, 2017, No 1, pp. 55–64.

19. Khaskov, M.A., Melnikov, D.A., Kotova E.V., Podbor temperaturno-vremennykh rezhimov otverzhdeniya epoksidnykh svyazuyushchikh s uchetom masshtabnogo faktora [Selection of temperature-time regimes of curing epoxy binderstaking into account the scale factor], Klei. Germetiki. Tekhnologii, 2017, No 10, pp. 24–32.


Review

For citations:


Nasonov F.A., Aleksashin V.M., Melnikov D.A., Bukharov S.V. Zinc-stearate modification of epoxy resins and carbon plastics based on them and its influence on the basic technological properties of the composition. Voprosy Materialovedeniya. 2018;(3(95)):146-156. (In Russ.) https://doi.org/10.22349/1994-6716-2018-95-3-146-156

Views: 357


ISSN 1994-6716 (Print)