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Electrochemical deposition of nanocrystalline Ni–W coatings from citrate electrolytes

https://doi.org/10.22349/1994-6716-2020-101-1-111-117

Abstract

In this paper, requirements for wear-resistant coatings of Ni–40%W manufactured by electrochemical deposition are determined, and the electrolyte stability is studied. The influence of temperature and current density on the deposition of the Ni–W alloy from a citrate electrolyte was researched, and the optimal deposition mode was found. The maximum operating time of the electrolyte is established by the dependence of the current efficiency for the Ni–W alloy on the electric power transmission. The necessity of using membrane electrolyzers during the deposition of nickel-tungsten coatings is substantiated.

About the Authors

A. V. Krasikov
NRC “Kurchatov Institute” – CRISM “Prometey”
Russian Federation
Cand Sc. (Chem)


A. D. Bykova
NRC “Kurchatov Institute” – CRISM “Prometey”
Russian Federation


M. V. Merkulova
St Petersburg State Institute of Technology
Russian Federation


M. A. Markov
NRC “Kurchatov Institute” – CRISM “Prometey”
Russian Federation
Cand Sc. (Eng)


References

1. V a s k o , A . T ., Elektrokhimiya molibdena i volframa [Electrochemistry of molybdenum and tungsten], Kiev: Naukova dumka, 1977.

2. S t e p ano va , L . I . , B od r ykh , T . I . , P u r ov sk aya , O . G . , S v i ri do v a , T . V ., Funktsionalnye nanostrukturirovannye plenochnye pokrytiya, soderzhashchie W, Mo i/ili ikh oksidy [Functional nanostructured membrane coatings containing W, Mo and / or their oxides], Nanotekhnika, 2005, No 2, pp. 54–60.

3. K r a s ik ov , A . V. , P e r vu kh in a , M . S ., Tekhnologicheskie osobennosti naneseniya pokrytiy iz nanostrukturirovannykh splavov nikel-volfram metodom elektrokhimicheskogo osazhdeniya [Technological features of coating from nanostructured nickel–tungsten alloys by electrochemical deposition], Voprosy Materialovedeniya, 2011, No 3 (67), pp. 117–124.

4. K r a s ik ov , A . V., Issledovanie tekhnologicheskikh parametrov osazhdeniya splava Ni–W iz pirofosfatno-ammoniynogo elektrolita [Research of technological parameters of deposition of Ni–W alloy from pyrophosphate-ammonium electrolyte], Voprosy Materialovedeniya, 2012, No 1(69), pp. 68–73.

5. F u r mo n , M . S . , K r a s iko v , A .V ., Sostav, mikrotvordost i struktura pokrytiy iz splavov nikel– volfram, poluchennykh metodom elektrokhimicheskogo osazhdeniya [Composition, microhardness and structure of coatings of nickel–tungsten alloys obtained by electrochemical deposition], Voprosy Materialovedeniya, 2012, No 1 (69), pp. 74–79.

6. Z a k h a r o v a , A .A ., Elektroosazhdenie molibdena i volframa s metallami podgruppy zheleza [Electrodeposition of molybdenum and tungsten with metals of the iron subgroup]: Abstract of thesis for the degree of candidate of sciences in engineering, Leningrad, 1981.

7. Y a ma s a k i T ., High-strength Nanocrystalline Ni–W Alloys Produced by Electrodeposition, Mater. Phys. Mech., 2000, V. 1, pp. 127–132.

8. Y o un es , O . , G i l e ad i , E ., Electrodeposition of High Tungsten Content Ni/W Alloys, Electrochemical and Solid State Letters, 2000, V. 12, No 3, pp. 543–545.

9. E l i a z , N . , S r id h a r , T . M . , G il e a d i , E . , Synthesis and Caracterisation of Nickel Tungsten Alloys by Electrodeposition, Electrochimica Acta, 2005, V. 50, pp. 2893–2904.

10. G o lo v i n , D . A ., Sovershenstvovanie protsessa galvanicheskogo zolocheniya iz slabokislykh i neytralnykh elektrolitov [Improving the process of galvanic gilding from slightly acidic and neutral electrolytes]: Abstract of thesis for the degree of candidate of sciences in engineering, Ivanovo, 1994.

11. B e r k h , O . , B u r s t e in , L . , S h a c h a m- D i a ma n d , Y . , G i l e a d i, E ., The Chemical and Electrochemical Activity of Citrate on Pt-Electrodes, Journal of The Electrochemical Society, 2011, No 158 (6), pp. F85–F91.

12. Diagrammy sostoyaniya dvoynykh metallicheskikh sistem [Diagrams of binary metal systems], Lyakishev, N.P., (Ed.), Moscow: Mashinostroenie, 2001. V. 3.


Review

For citations:


Krasikov A.V., Bykova A.D., Merkulova M.V., Markov M.A. Electrochemical deposition of nanocrystalline Ni–W coatings from citrate electrolytes. Voprosy Materialovedeniya. 2020;(1(101)):111-117. (In Russ.) https://doi.org/10.22349/1994-6716-2020-101-1-111-117

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ISSN 1994-6716 (Print)