Preview

Voprosy Materialovedeniya

Advanced search
Open Access Open Access  Restricted Access Subscription Access
No 1(101) (2020)
View or download the full issue PDF (Russian)

METALS SCIENCE. METALLURGY

5-15 368
Abstract

The temperature-strain conditions of dynamic and static recrystallization during hot deformation were determined at a rate of 1 sec–1 for medium-carbon steel microalloyed with titanium, boron, and vanadium containing different amounts of niobium. It was found that under hot rolling conditions niobium prevents the completion of dynamic recrystallization, and at temperatures below 970°C it drastically slows down static recrystallization in the pauses between successive reductions.

16-26 244
Abstract
The paper presents the results of study of changes in the structure, impact and crack resistance in two sections of the simulated heat-affected zone of low-carbon low-alloy steel with a guaranteed yield strength of 420 MPa (section with large grain and section of complete recrystallization). The simulation of various thermal welding cycles was performed on the Gleeble 3800 complex.
27-34 570
Abstract
The article discusses a method of improving the cold resistance of steels of a ferrite-pearlite class. It has been established that the process of programmed hardening, combined with an additional medium temperature tempering, has a positive effect on the cold resistance of thermally improved 09G2S steel. The mechanical properties of steel grade 09G2S were determined before and after additional tempering at mediumtemperature. It is shown that the new technology allows the critical temperature of brittleness, determined by the criterion of the energy intensity of failure, to be shifted to lower temperatures by 15°C, and at the same time to increase the impact strength of 09G2S steel three times more at a temperature of minus 90°C without changing its strength properties.
35-43 342
Abstract
The paper studies the 15Kh2MFA steel structures at various sections of the welded joint performed without heat treatment after welding with low-carbon surfacing. It is shown that there are three zones in lowcarbon surfacing, which differ in the content of chemical elements passing from the base metal to the deposited one, as well as in the tendency to form hardened structures during welding.
44-54 1253
Abstract
The paper studies chemical composition, structure and mechanical properties of the heat-resistant nickel EP648 alloy obtained by deformation, die project casting and selective laser melting. It is shown that the deformed material is characterized by low porosity, high impact strength and ductility, the cast material has large grains, high long-term strength and low-cycle fatigue. The material obtained by selective laser melting is characterized by an increased content of oxygen and nitrogen, fine-grain structure with large variation in grain size strongly expressed and heredity, and also high short-term strength.
55-62 255
Abstract

It is known that the solidification of melts under the influence of external factors leads to the formation of a fine-grained structure in the work pieces which improves the mechanical characteristics of finished metal products. The production of lengthy profiles with a high level of mechanical properties in a short production cycle is a complex interdisciplinary task of great practical importance. The paper presents results of research of the properties of products from aluminum alloy V95, which were obtained by continuous vertical casting combined with deformation in the solid-liquid state during solidification. A diagram of a device that implements such a process of combining is presented; its operation is reviewed. Also, a description is given of a method for producing flat work pieces and sample preparation for studying their mechanical characteristics and microstructure.

As research shows the metal products have a fine-grained structure with a dense directional arrangement of dislocations. The grain boundaries are wide, uneven, consisting of grids and dislocation plexuses. During the melt solidification a thin directional dislocation structure is formed in the crystallizer of the device providing increase of the mechanical characteristics of metal products without additional processing, and there are no shrinkage defects. The possibility of obtaining long metal products with high mechanical characteristics for a short production cycle with reduced power costs was shown.

63-73 389
Abstract
The relationship of the first and second laws of thermodynamics based on their energy nature is considered. It is noted that the processes described by the second law of thermodynamics often take place hidden within the system, which makes it difficult to detect them. Nevertheless, even with ideal mixing, an increase in the internal energy of the system occurs, numerically equal to an increase in free energy. The largest contribution to the change in the value of free energy is made by the entropy of mixing, which has energy significance. The entropy of mixing can do the job, which is confirmed in particular by osmotic processes.

FUNCTIONAL MATERIALS

74-84 378
Abstract
The paper describes conducted feasibility study and scientific and technical basis for creation of technology for drilling tools with diamond-carbide cutting elements. The results of technological processes of production of diamond-carbide inserts (DCI) manufactured by Technological Institute for Superhard and Novel Carbon Materials (TISNUM), which are designed for operation and implementation in various drilling conditions were presented. The DCI differentiated physic-chemical and performance characteristics, depending on the physic-mechanical properties of rocks formations, the particular construction of wells and other drilling conditions. A complex of studies of physical and mechanical properties of DCI, their relationship with the structural and technological factors, performance of bits equipped with DCI, the nature of bits wear were conducted, including pilot testing of new polycrystalline diamond compact bits (PDC bits) with polycrystalline diamond cutters produced by TISNUM at the facilities of JSC Gazprom Neft. The possibilities of industrial production of DCI and premium drilling bits on the basis of TISNUM technologies are shown, which will ensure demands of the Russian oil and gas industry, allowing import dependence elimination, and in future start of export. Ultimately, by 2025, with the help of new technologies, it will be possible to occupy up to 25– 30% of the global market for drilling tools and equipment.
85-96 406
Abstract

The paper presents results of studies of the optical and electromagnetic properties of the WO3/rGO electrochromic nanocomposite films obtained by mechanical spraying of a water-based dispersed solution with WO3/GO particles and heat treatment (annealing) at a temperature of 300°C in an inert argon atmosphere for 24 hours. As a result, an electrically conductive phase of reduced graphene oxide rGO and crystalline WO3 were formed.

97-103 274
Abstract
This article presents the results of the development of technology for producing clad powder and coatings based on it. The possibility of obtaining a clad powder using high-speed mechanosynthesis in disintegrator plants is shown on the example of the Hadfield steel – aluminum powder composition.
104-110 305
Abstract
This article explores the characteristic and particular features of manufacturing nanostructured composite coatings with high microhardness from agglomerated powders of Kh20N80-WC system manufactured by high-speed mechanosynthesis. The properties of the functional coatings deposited by both supersonic cold gas-dynamic and microplasma spraying are studied.
111-117 378
Abstract
In this paper, requirements for wear-resistant coatings of Ni–40%W manufactured by electrochemical deposition are determined, and the electrolyte stability is studied. The influence of temperature and current density on the deposition of the Ni–W alloy from a citrate electrolyte was researched, and the optimal deposition mode was found. The maximum operating time of the electrolyte is established by the dependence of the current efficiency for the Ni–W alloy on the electric power transmission. The necessity of using membrane electrolyzers during the deposition of nickel-tungsten coatings is substantiated.
118-125 254
Abstract
The possibility of high electrical conductivity of dry sliding electrical contact against molybdenum counterbody was studied. It was found that metals W and Cu were not able to form a sliding electrical contact with high wear resistance at current density higher 100 A/cm2 . The characteristics of the contacts of iron containing metals were slightly better than the contact characteristics of non-ferrous metals due to weaker adhesion. Using X-ray phase analysis, it was shown the absence of oxides in the sliding zone of non-ferrous metals. This led to their strong wear and contact’s low electrical conductivity. In the contact zone of iron containing samples the formation of FeO was observed that made it possible to reduce wear. This means that high electrical conductivity is unattainable in sliding with current collection against molybdenum.

POLYMERIC COMPOSITE MATERIALS

126-138 1680
Abstract
This article discusses the main classification criteria for fiber-based hybrid polymer composite materials. Their distinctive features are analyzed; examples of hybrid PCMs are given. The experience of FSUE VIAM in the creation of hybrid PCMs is considered.
139-147 309
Abstract
The article considers approaches and requirements for fire-safety characteristics definition of composite polymeric materials in shipbuilding. The results of experimental determination for such characteristics for three-layer composite polymeric material and fiberglass layer as an example are provided. The need for the development of domestic regulatory documentation on the correct requirements for testing multilayer PCM and data interpretation has been identified.
148-153 231
Abstract
Results of simulation and experimental research allowed us to obtain values of deformation characteristics of carbon fabric structure. Experimental data were processed according to methods of measurement of state system for ensuring the uniformity of measurements. Theoretical and experimental data have good coincidence, confirming high quality of mechanic-analytical model for deformation of the carbon fabric structure.

CORROSION AND PROTECTION OF METALS

154-162 302
Abstract

The paper studies stress corrosion cracking (SCC) of low carbon low alloyed steels. It is shown that the use of eddy current method allows us to evaluate modifications of fine structures associated with the processes of initiation and growth of stress corrosion cracks. The dependences of the incubation time on the value of the macroelasticity limit σ0 are given. It is noted that the increase in the value of σ0 leads to an increase in the time before the initiation of the first crack. This can be explained: the limit of macroelasticity determines the beginning of microplastic flow in the material. On the basis of experimental data, the analytical dependence of the incubation period of the SCC on the value of the macroelasticity limit is obtained. The calculation error did not exceed 10%. A parameter is proposed for assessing the state of the material subject to SCC. It allows recording the passage of the stages of accumulation of micro-damages and the moment of exhaustion of a significant part of the material resource before the appearance of multiple surface macro-cracks according to the data of eddy current measurements.

163-175 365
Abstract
The paper investigates aspects of the development of corrosion processes under conditions of moisture condensation in the gas phase in the presence of carbon dioxide, which lead to the formation of local damage. The authors developed and tested a methodology for conducting steels corrosion testing The causes of the formation and the corrosive effect of moisture condensation on steel under conditions of carbon dioxide corrosion at gas production facilities are analyzed. It was found that at elevated temperatures, when the temperature difference is higher, more moisture condenses on the surface of the steel, which leads to an increase in the rate of both general and local corrosion by 2–3 times, compared to room temperature. The increased localization of corrosion processes under conditions of moisture condensation and the presence of CO2 makes the depth index of steel corrosion much higher than the general corrosion rate. When assessing the corrosiveness of environments with condensation of the aqueous phase, the rate of corrosion associated with the depth of the observed corrosion damage should be taken into account. According to the test results, it was determined that samples from the weld compared with the sample from the main body of the pipe differ in the degree of localization of corrosion in conditions of moisture condensation.


ISSN 1994-6716 (Print)