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Voprosy Materialovedeniya

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No 4(104) (2020)
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METALS SCIENCE. METALLURGY

5-16 281
Abstract

The kinetics of austenite grains' growth upon heating has been investigated, and the processes of dynamic and static recrystallization occurring under different modes of plastic deformation (reduction pattern, deformation temperature) of high-strength steels with various microalloying complexes have been studied. The research made it possible to reveal the thermal deformation conditions for the formation of a finely dispersed homogeneous structure of steel. Technological recommendations have been developed for the production of high-strength steels depending on their microalloying (vanadium, niobium).

17-31 272
Abstract

The article presents the results of a study of the relationship between strength and performance (temperatures of ductile-brittle transition Tdb and zero plasticity NDT, critical opening at the crack tip CTOD at a test temperature of —40°C) on the structure parameters of thick plate products made of low-carbon low-alloy steels with different contents of basic alloying and microalloying elements.

 

32-47 239
Abstract

This work presents the experimental data obtained using an integrated approach in the study of the chemical, crystallographic and morphological homogeneity of the structure of a heat-resistant material on a nickel base with carbide-intermetallic hardening and an increased content of the γ-phase, synthesized on single-crystal substrates of various compositions with CHO <001> in Z-direction. Using the proposed method for studying the capabilities and certification of different-level structural structures of samples in the initial state and after thermal study of the impact. The analysis was carried out using the system for EBSD analysis integrated into the scanning electron microscope and the software package for the analysis of electron microscopic images.

 

48-63 452
Abstract

The results of tests on the FCGR (fatigue crack growth rate) of compact specimens of eccentric tension using a crack opening (COD) sensor under conditions of an asymmetric loading cycle R=0.1 at room and elevated temperatures are presented. The relationship between the conditions of force loading of preliminary growth of the initial fatigue crack is considered. The values of the effective stress intensity factor Keff were obtained, which is an important estimate for interpreting the observed character of crack growth. A comparison of the properties of the cyclic crack resistance of the VZh175-ID alloy with the properties of foreign analogues Rene 88DT, Inconel 625 SLM and domestic ones - EP741NP, EK151-ID is presented. The influence of the test temperature on the growth rate is shown. The hypothesis about the linear dependence of the parameters of the Paris equation is tested.

64-78 432
Abstract

The paper presents the scientific, technical and technological aspects in the field of creating new high-temperature materials for parts of the hot section of gas turbine engines (GTE) with operating temperatures exceeding those existing in GTE. More refractory metallic materials for the creation of new high-heat-resistant alloys used for the manufacture of rotor and nozzle blades and other parts of promising gas turbine engines based on NiAl-Ni3Al, Co-Cr-Re, Pt-Al, Nb-Si, Mo-Si-B systems have been investigated. It is shown that, depending on the composition of the selected matrix, the working temperature of heat-resistant alloys increases to 1300-1500°С, which is significantly higher than the existing nickel heat-resistant alloys.

79-86 519
Abstract

Among titanium alloys, modern α- and pseudo-α-alloys occupy a special place due to the unique combination of their mechanical properties, corrosion resistance, low density and high specific strength, which determines their effectiveness in various industries. Analysis of structural materials used for heat exchange equipment of nuclear power plants showed that the increase in the efficiency and compactness of tube systems made of a-titanium alloys is constrained by their thermal conductivity characteristic, which does not exceed 89 W/(m·K) at a temperature of 20°C. An exception is the VT1-0 grade alloy, the scope of which is limited to a maximum operating temperature of no more than 250°C. The paper considers the results of studies of a new titanium alloy of the Ti-Zr-Al-O composition with increased thermal conductivity for pipe systems of power equipment.

 

FUNCTIONAL MATERIALS

87-94 313
Abstract

This work presents the results of studying the features of the casting process of glass-coated microwires of alloys based on silver, which has a near-zero TCR, and nickel, which has a high thermo emf.

 

95-108 323
Abstract

In this work, an experimental modeling of the technology for producing a matrix by sintering a diamond-containing briquette with a filler of tungsten monocarbide powder impregnated with a Fe-C eutectic melt in a vacuum is carried out. The microstructure, elemental and phase compositions of the products formed in the process of sintering a diamond-containing matrix with impregnation with a Fe-C eutectic melt in vacuum have been studied by scanning electron microscopy, X-ray spectral and X-ray phase analyzes, and Raman spectroscopy. It was found that the matrix consists of 61.0% tungsten carbide phases, 17.0% of iron carbide, 16.5% of α-Fe, and 5.5% of graphite. The eutectic Fe-C alloy, which serves as a matrix binder, consists of a ferrite-pearlite metal base with graphite inclusions. It is shown that at the diamond - matrix interface, graphite inclusions are formed not as a continuous layer, but as discontinuous areas along the perimeter of diamond grains. The microhardness of the WC-based matrix impregnated with the Fe-C melt is ~ 11 GPa, which is more than 3 times higher than the microhardness of the WC-Co-Cu hard alloy matrix obtained by sintering with copper impregnation.
The research results can be used in the development of technology for the manufacture of wear-resistant matrices of diamond tools of a wide class used in the processing of materials with a high level of hardness.

109-112 239
Abstract

The article presents research results on the development of a precision alloy of the Al-Mg-Ce-La-Y system for obtaining thin films by magnetron sputtering. Thin films are used to create electronic components on their basis.

 

113-116 215
Abstract

This paper presents the results on the development of an alloy in the tellurium - copper - cerium system used for the manufacture of functional coatings using the technologies of supersonic cold gas-dynamic spraying. Coatings from the specified alloy are used for the manufacture of photocathodes of photoelectronic devices operating in the UV spectral region.

117-120 198
Abstract

The paper presents the results of research and development of glasses for insulation of cast microwires of the PbO - SiO2 - Na2O - InO2 - SnO2 system. The optimal composition has been determined, which makes it possible to establish a stable process of casting microwires from indium and tin with a length of more than 1000 meters. It is shown that from such microwires it is possible that small base fusible fuses with a high melting current density could be manufactured.

 

121-131 202
Abstract

The article presents the results of a study of the catalytically active system Ni-Al-Al(OH)3-Ca(OH)2-Mg(OH)2 for efficient synthesis gas production. A technology for obtaining volumetric porous functional coatings has been developed using the method of supersonic cold gas-dynamic spraying. The advantages of this method and its possibilities from the point of view of producing synthesis gas with high activation energy are shown.

132-143 425
Abstract

This work studies the effect of the relative content of Al2O3 nanofibers on the compaction, phase composition, and physicomechanical properties of composites based on ZrO2 obtained by free vacuum sintering. It was found that in the process of manufacturing composites, nanofibers are sintered into Al2O3 grains of complex, elongated shape, which form a solid, frame-reinforcing structure. The relative density of composites with 5 wt. % and 10 wt. % of nanofibers, decreases up to 95%. It is shown that in all sintered samples the tetragonal modification of ZrO2 acts as the main phase, and the different content of nanofibers affects the amount of cubic and monoclinic modifications of ZrO2. It was found that addition of 5 wt. % and 10 wt. % of Al2O3 nanofibers increases the microhardness of the composite by 11% and crack resistance by 46%.

POLYMERIC COMPOSITE MATERIALS

144-157 259
Abstract

Ballistic-resistant organoplastics made from layers of aramid fabric, adhesively bonded by a binder film, exhibit an increased tendency to absorb moisture, water and technical fluids in comparison with organoplastics monolithic structures. The absorption of liquids is anisotropic and manifests itself most intensively through the butt ends of the samples. The use of protective paintwork ensures stability of the characteristics of ballistic-resistant materials when exposed to environmental factors (environment, water, fuel, oil, natural climatic conditions).

 

158-169 488
Abstract

The roughness of the friction surface of antifriction carbons used in sliding friction units lubricated with water affects the tribotechnical characteristics during the running-in process. This article experimentally substantiates the range of optimal surface roughness formed during mechanical cutting of carbon plastics in terms of tribotechnical efficiency. The results of a series of tribotechnical tests using various methods under various conditions (contact pressure, sliding speed, counterbody materials) are presented. The relationship between the initial roughness and the effectiveness of a running-in coating based on FORUM® polytetrafluoroethylene powder is established.

CORROSION AND PROTECTION OF METALS

170-181 306
Abstract

This paper examines factors causing the darkening of items made of silver alloys in showcases and storehouses of museums, the authors analyze methods to prevent this undesirable process. The results of studies of different methods for preventing tarnishing of silver alloys are also presented.

STRUCTURAL-WORKING STRENGTH AND SERVICEABILITY OF MATERIALS

182-191 262
Abstract

A crack front straightness is one of the test result validity criteria for fatigue precracked static fracture toughness specimens. Actually, the ideally straight crack front cannot be reached due to the presence of residual stress. This is particularly actual for specimens cut out of welded joints containing the residual welding stress (RWS). One of the techniques allowing to lower the RWS effect is a local side compression of specimens. Its efficiency has been proved in physical testing however no quantitative assessments are known in the literature. This work comprises FEM simulation of welding, sampling and side compression processes. The effect of local compression on base metal containing no residual stress is also investigated.
It has been found that in the course of local side compression the initial residual stress field caused by welding and specimen making is replaced by another field showing stress gradients more favourable for getting the fatigue crack shape meeting the validity criteria of test results as per approved test methods. The calculation results show that the complete removal of residual stress as in base metal as in welded specimens is not feasible in the range of actual practicable degrees of compression.

RADIATION MATERIALS SCIENCE

192-199 259
Abstract

The paper presents the research results on determining the mechanical characteristics of the metal samples cut out from the nozzles and the cylindrical shell at the nozzles zone of the VVER-440 reactor vessel after 45 years of operation.



ISSN 1994-6716 (Print)