METALS SCIENCE. METALLURGY
FUNCTIONAL MATERIALS
When thermal diffusion metallization of diamond with iron occurs at the diamond-metal interfacial zone, the formation of an intermediate layer strongly adhered to the diamond also takes place. The intermediate layer has a complex structural phase composition comprising a mixture of iron phases, a solid solution of carbon in iron and graphite of variable composition. An intermediate layer on the surface of diamond could be formed by solidification of the liquid phase with the eutectic composition resulting from the eutectic melting of the diamond-iron contact pairs. However, this assumption requires additional research to confirm it, and special experiments using highly sensitive research methods.
Under the heating conditions specified in the experiment samples of nickel-diamond and cobaltdiamond cause intense catalytic graphitization of diamond with the formation of numerous traces of erosion on its surface. The observed weak adhesive interaction of these metals with diamond is probably due to the high melting temperatures of the Ni-C and Co-C eutectics, which does not allow the metals to react with diamond under given experimental conditions.
POLYMERIC COMPOSITE MATERIALS
The paper studies tribotechnical properties, hardness and density of composites based on ultra-high molecular weight polyethylene (UHMWPE) filled with sulfur, diphenylguanidine (DFG) and 2-
mercaptobenzothiazole (MBT) and their mixtures. It has been established that the introduction of selected fillers has practically no effect on hardness and density of the composites, but leads to a significant (by 2–3 times) increase in the wear resistance of materials. Using electron microscopy, it has been established that secondary structures are formed in composites containing MBT that protect the surface layer of the material from wear. Using IR spectroscopy, it was established that tribochemical reactions occur during the wear of composites with the formation of hydroxyl and carbonyl groups. The developed materials UHMWPE / MBT and UHMWPE / FGD / MBT have high wear resistance and can be used as materials for tribological purposes.